非粮生物质高值化利用,到底是什么?全球谁在领跑?Non-Grain Biomass High-Value Utilization: What Exactly Is It and Who Leads Globally?
【绿色燃料国际商务网】获悉,围绕“非粮生物质高值化利用到底是什么、全球谁在领跑”这一行业关注话题,DT产业研究院日前系统梳理了非粮生物质炼制的技术演进、全球格局与中国实践,试图说清三个问题:非粮生物质炼制到底是什么、全球谁在领跑、中国在做什么。
从资源禀赋看,寻找能够替代石油的原料已成共识。《BP世界能源统计2020》数据显示,2019年底全球石油探明储量2446亿吨,按当年开采量只能供应49.9年;中国储量36亿吨,仅占全球1.5%,只能供应18.7年。而地球每年经光合作用产生的生物质约1730亿吨,其中70%为碳水化合物(纤维素、淀粉等),20%为木质素,这是目前唯一可能替代化石资源的天然碳源。
“生物质炼制”概念最早于1982年在《Science》上提出,核心理念是学石油炼制的思路,把生物质原料中每一种组分都分离出来、分别转化为不同产品,实现原料全组分利用与产品价值最大化。“非粮生物质高值化利用”,正是这一概念在中国产业语境下的具体表达——不用粮食,用秸秆、木屑、农林废弃物向高附加值化学品和材料转化。
技术路线上,生物质炼制经历三代演进:第一代以玉米、甘蔗、菜籽油等粮食为原料,技术成熟但“与人争粮、与粮争地”;第二代改用秸秆、木屑等木质纤维原料,但主要只取纤维素,木质素当废料烧掉,碳转化率低;第三代即当前的木质纤维生物质炼制,目标是纤维素、半纤维素、木质素各归各位的全组分利用,碳转化率理论上无损失。文章特别指出,木质素热值27.0MJ/Kg,半纤维素热值仅13.6MJ/Kg,但从化工原料角度看,木质素是酚类聚合物,是芳烃化合物的天然来源,烧掉它等于把石油里的芳烃馏分当柴火烧。
全球格局方面,北美走“制浆造纸厂升级”路线。1994年美国林产和造纸工业协会提出“复合型森林生物质精炼”概念;加拿大Fortress Paper在魁北克省启动半纤维素提取项目,从桦木中提取木糖和糠醛;CelluForce公司生产纤维素纳米晶体并获斯伦贝谢投资;不列颠哥伦比亚省投资225万美元用于纤维素纤丝项目研究,Kruger公司建成全球首家产量5吨/天的纤维素纤丝示范工厂。但北美也有教训,杜邦在爱荷华州的纤维素乙醇工厂最终出售退出,DSM与Poet合资项目经历反复调整,说明技术领先不等于产业化一定走通。
欧洲政策框架最为完善。2013年欧盟提出BRIDGE计划加速生物基产品市场化,2016年BIOFOREVER示范项目启动、14家欧洲公司参与。芬兰UPM在德国Leuna建成全球首个将固体木材转化为生物基化学品的工业规模生物炼厂,年产22万吨生物化学品、投资7.5亿欧元,2025年底产出首个商业化产品工业糖,但糖到化学品转化环节的工程纠正导致综合商业生产推迟,UPM为此计提3.73亿欧元减值。芬兰Metsä集团2017年投产的生物质精炼厂纸浆产能130万吨/年(80万吨针叶浆+50万吨阔叶浆),同时生产妥尔油、松节油、生物能源和沼气,能源不仅自给还能为所在小镇供热。意大利M&G集团联合安徽国祯集团在阜阳建设生物质精炼厂,年转化130多万吨纤维生物质。
巴西是全球最大甘蔗乙醇生产国,产业成熟度领先,但从“非粮”视角恰是反衬,其也在用利润反哺非粮探索:Suzano公司2016年推出桉木纤维绒毛浆产品Eucafluff,桉树皮每年300万至600万吨产量已用于提取己糖和转化化学品。日本则走精细化路线,日本制纸集团开发纤维素基高阻隔包装材料Shield Plus,用纤维素做高附加值功能材料逐步替代塑料。
中国的政策力度全球最大。2023年1月,工信部、发改委、财政部等六部门联合印发《加快非粮生物基材料创新发展三年行动方案》,明确到2025年部分非粮生物基产品竞争力要与化石基产品相当;2025年工信部与农业农村部联合发布典型案例入围名单,35个项目入选,生物基材料市场预计突破1200亿元。产业层面,圣泉集团2023年5月在黑龙江大庆建成全球首个百万吨级生物质精炼一体化项目,占地1500亩、投资20余亿元、年处理秸秆50万吨,产品覆盖纤维素制品、糠醛、高活性木质素、生物炭、木糖醇、L-阿拉伯糖、生物航煤、硬碳负极材料等上百种;太阳纸业走木片组分深度分离路线;龙力生物2011年建成大规模木质纤维生物质精炼全组分利用生产线,年处理20万吨玉米芯。文章认为,中国不缺政策、不缺原料、不缺单点技术突破,当前核心任务是把单点连成产业链的系统整合;严格来说,全球目前还没有真正意义上的领跑者。
[Green Fuel International Business Network] has learned that, around the industry topic of "what exactly is the high-value utilization of non-grain biomass and who is leading globally," DT Industry Research Institute recently systematically reviewed the technological evolution, global landscape and Chinese practice of non-grain biomass refining, seeking to clarify three questions: what exactly non-grain biomass refining is, who is leading globally, and what China is doing.
In terms of resource endowment, finding feedstock that can replace oil has become a consensus. According to the "BP Statistical Review of World Energy 2020," global proven oil reserves stood at 244.6 billion tonnes at the end of 2019, sufficient for only 49.9 years at that year's extraction rate; China's reserves were 3.6 billion tonnes, only 1.5% of the global total, sufficient for only 18.7 years. In contrast, the Earth produces about 173 billion tonnes of biomass annually through photosynthesis, 70% of which is carbohydrates (cellulose, starch, etc.) and 20% lignin—currently the only natural carbon source that could replace fossil resources.
The concept of "biomass refining" was first proposed in Science in 1982, with the core idea of learning from petroleum refining: separating every component of biomass feedstock and converting them into different products to achieve full-component utilization of feedstock and maximized product value. "High-value utilization of non-grain biomass" is precisely the concrete expression of this concept in the Chinese industrial context—not using grain, but using straw, wood chips and agricultural and forestry waste and converting them into high-value-added chemicals and materials.
In terms of technology routes, biomass refining has undergone three generations of evolution: the first generation used food crops such as corn, sugarcane and rapeseed oil as feedstock—mature technology but "competing with people for food and with food for land"; the second generation switched to lignocellulosic feedstock such as straw and wood chips, but mainly extracted only cellulose, burning lignin as waste, with low carbon conversion; the third generation, today's lignocellulosic biomass refining, aims at full-component utilization with cellulose, hemicellulose and lignin each in its place, with theoretically no carbon conversion loss. The article particularly notes that lignin has a calorific value of 27.0 MJ/kg while hemicellulose has only 13.6 MJ/kg, but from the perspective of chemical feedstock, lignin is a phenolic polymer and a natural source of aromatic compounds—burning it is like burning the aromatic fraction of petroleum as firewood.
In terms of the global landscape, North America follows a "pulp and paper mill upgrade" route. In 1994, the American Forest & Paper Association proposed the concept of "integrated forest biorefinery"; Canada's Fortress Paper launched a hemicellulose extraction project in Quebec, extracting xylose and furfural from birch; CelluForce produces cellulose nanocrystals and received investment from Schlumberger; British Columbia invested USD 2.25 million in research on a cellulose filament project, and Kruger built the world's first cellulose filament demonstration plant with an output of 5 tonnes/day. But North America also offers lessons: DuPont's cellulosic ethanol plant in Iowa was eventually sold and exited, and the DSM-Poet joint venture underwent repeated adjustments, showing that technological leadership does not guarantee successful industrialization.
Europe has the most complete policy framework. In 2013, the EU proposed the BRIDGE program to accelerate the marketization of bio-based products, and in 2016 the BIOFOREVER demonstration project was launched with the participation of 14 European companies. Finland's UPM built the world's first industrial-scale biorefinery converting solid wood into bio-based chemicals in Leuna, Germany, producing 220,000 tonnes of bio-based chemicals per year with an investment of EUR 750 million; it produced its first commercial product, industrial sugar, at the end of 2025, but engineering corrections in the sugar-to-chemicals conversion stage delayed integrated commercial production, and UPM took a EUR 373 million impairment charge for this. Finland's Metsä Group put its biomass refinery into operation in 2017 with pulp capacity of 1.3 million tonnes/year (800,000 tonnes of softwood pulp plus 500,000 tonnes of hardwood pulp), while also producing tall oil, turpentine, bioenergy and biogas; its energy is not only self-sufficient but also supplies heat to the town where it is located. Italy's M&G Group, together with Anhui Guozhen Group, built a biomass refinery in Fuyang that converts more than 1.3 million tonnes of fibrous biomass per year.
Brazil is the world's largest producer of sugarcane ethanol and leads in industrial maturity, but from a "non-grain" perspective this is a contrast, and Brazil is also using profits to feed back into non-grain exploration: Suzano launched its eucalyptus fiber fluff pulp product Eucafluff in 2016, and the 3 million to 6 million tonnes of eucalyptus bark produced each year are already used to extract hexose and convert it into chemicals. Japan follows a refined route, with Nippon Paper Group developing the cellulose-based high-barrier packaging material Shield Plus, using cellulose to make high-value-added functional materials that gradually replace plastics.
China's policy support is the strongest in the world. In January 2023, six departments including MIIT, the NDRC and the Ministry of Finance jointly issued the "Three-Year Action Plan for Accelerating the Innovative Development of Non-Grain Bio-Based Materials," specifying that by 2025 some non-grain bio-based products should be competitive with fossil-based products; in 2025 MIIT and the Ministry of Agriculture and Rural Affairs jointly released a shortlist of typical cases, with 35 projects selected, and the bio-based materials market is expected to exceed RMB 120 billion. At the industrial level, Shengquan Group built the world's first million-tonne-class integrated biomass refining project in Daqing, Heilongjiang, in May 2023, covering 1,500 mu, with investment of more than RMB 2 billion and an annual processing capacity of 500,000 tonnes of straw; its products cover more than a hundred items including cellulose products, furfural, highly active lignin, biochar, xylitol, L-arabinose, bio jet fuel and hard carbon anode materials. Sun Paper follows a route of deep separation of wood chip components; Longlive Bio-Technology built a large-scale lignocellulosic biomass refining production line for full-component utilization in 2011, processing 200,000 tonnes of corn cobs per year. The article argues that China does not lack policies, feedstock or single-point technological breakthroughs; the core task now is to connect single points into the systemic integration of an industrial chain; strictly speaking, there is currently no true global leader.
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